In this work, an effective, task specific, dicationic, podand-like ionic liquid was synthesized and applied
to improve the capability features of click reaction. Moreover, to broaden the scope and decreasing the
serious limitations of preparation methods of organic azides, a simple green procedure for the
preparation of alkyl azides, the fundamental starting materials in click reactions, from alcohols under
solvent-free conditions and microwave irradiation has been reported, for the first time.
