چکیده :

In this work, Fe2? supported on hydroxyapatite-core–shell-c-Fe2O3 nanoparticles (c-Fe2O3–HAp-Fe2? NPs) has been prepared and characterized by Fourier transform infrared spectroscopy, X-ray diffraction, transmission electron microscopy, scanning electron microscopy, and vibrating sample magnetometry spectra. Then, c-Fe2O3–HAp-Fe2? NPs were used as an efficient, reusable and heterogeneous nanocatalyst for one-pot synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes via the one-pot condensation reaction of arylaldehydes and 2-naphthol under solvent-free conditions in good to excellent yields. This procedure has a lot of advantages such as very easy reaction conditions, simplicity in operation, short reaction time, high yield, and green aspects by avoiding toxic conventional catalysts and solvents. Additionally, c-Fe2O3–HAp-Fe2? NPs were easily recycled from the reaction mixture and were reused seven times without any loss in activity.

کلید واژگان :

c-Fe2O3–HAp-Fe2?  Magnetic nanoparticle  14H-dibenzo[a,j]xanthenes  Lewis acid  Nanocatalyst  Reusable catalyst



ارزش ریالی : 600000 ریال
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