The feasibility of using cascade neural networks to correlate the bubble points of ternary mixtures containing ionic liquids (ILs) and classical solvents was investigated. The systems investigated consisted of the ILs from the alkylimidazolium family with either the chloride, tetra°uoroborate, methylsulfate, or ethyl sulfate anions. The classical solvents investigated included 1-propanol, 2-propanol, ethanol, ethyl ethanoate, and water. A total of 272 bubble points were used in the training (205 data points) and testing (67 data points) stages. The optimized network comprised of nine neurons in the hidden layer and used the tangent-sigmoid and purelin functions as the activation functions in the hidden and output layers, respectively. This proposed network was able to correlate the ternary bubble points of both the training (AARD % ¼ 0:13% and R2 ¼ 0:9921) and the testing (AARD % ¼ 0:15% and R2 ¼ 0:9873) subsets with good accuracy, revealing the good correlative capability of the network. The statistical error analysis of all the data indicated an overall absolute average relative deviation (AARD %), mean square error (MSE ) and correlation coe±cient (R2) of 0.13%, 0.44% and 0.9909%, respectively.
کلید واژگان :Physicochemical property; property prediction; ionic liquid; ternary mixtures; bubble point; neural networks.
ارزش ریالی : 600000 ریال
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