چکیده :

The intensity of emitted light from CdSe quantum dots (QDs)–H2O2is described as a novel chemiluminescence (CL) reaction for determination of dysprosium. This reaction is based on the catalytic effect of Dy 3+ ions, causing a significant increase in the light emission, as a result of the reaction of quantum dots (QDs) with hydrogen peroxide. In the optimum conditions, this method was satisfactorily described by linear calibration curve in the range of 8.310 7 –5.010 6 M, the detection limit of 6.010 8 M, and the relative standard deviation for five determinations of 2.510 6 MDy3+ 3.2%. The main experimental advantage of the proposed method is its selective to Dy 3+ ions compared with common coexisting cations, therefore, it was successfully applied for the determination of dysprosium ions in water samples

کلید واژگان :

Quantum dots, Dysprosium, Chemiluminescence, Enhancement, Cadmium selenide



ارزش ریالی : 1200000 ریال
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