The intensity of emitted light from CdSe quantum dots (QDs)–H2O2is described as a novel chemiluminescence (CL) reaction for determination of dysprosium. This reaction is based on the catalytic effect of Dy 3+ ions, causing a significant increase in the light emission, as a result of the reaction of quantum dots (QDs) with hydrogen peroxide. In the optimum conditions, this method was satisfactorily described by linear calibration curve in the range of 8.310 7 –5.010 6 M, the detection limit of 6.010 8 M, and the relative standard deviation for five determinations of 2.510 6 MDy3+ 3.2%. The main experimental advantage of the proposed method is its selective to Dy 3+ ions compared with common coexisting cations, therefore, it was successfully applied for the determination of dysprosium ions in water samples
کلید واژگان :Quantum dots, Dysprosium, Chemiluminescence, Enhancement, Cadmium selenide
ارزش ریالی : 1200000 ریال
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جزئیات مقاله
- کد شناسه : 1142831533782909
- سال انتشار : 2013
- نوع مقاله : پذیرفته شده در مجلات Scopus ,ISI با 4>IF>
- زبان : انگلیسی
- محل پذیرش : Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
- IF مجله : 2.129
- ISSN : 1386-1425
- تاریخ ثبت : 1394/01/17 14:45:37
- ثبت کننده : بتول عرب سرخی میشابی
- تعداد بازدید : 291
- تعداد فروش : 0