The activity of Pd(II)-Schiff base complexmolecules grafted on the surface of Fe3O4@SiO2 particles were
investigated in the palladium-catalyzed coupling reactions of aryl halides with alkenes (Mizoroki-Heck
reaction) and phenylboronic acids (Suzuki-Miyaura reaction) in the absence of phosphorous ligands. This
method shows notable advantages such as heterogeneous nature of the catalyst, excellent yields, short reaction
times, easy preparation, simplicity of operation, and cleaner reaction profiles. The catalyst can be
separated from the reaction mixture by applying a permanent magnet externally and can be reused for several
times without significant loss of activity. Also, the amount of palladium leaching has been determined
by ICP analysis.
کلید واژگان :
Magnetic nanoparticles; Mizoroki-Heck and Suzuki-Miyaura reactions; Schiff base complex
